�g�q��p6� Buy Thionyl Chloride online from WorldOfChemicals. Recommended Use Laboratory chemicals. Thionyl chloride is a colorless to pale yellow liquid with a suffocating odor. ACGIH Threshold Limit Values (TLV) Remarks Upper Respiratory Tract irritation 2010 Adoption . Mohl by se též nazývat thionylchlorid.Jeho vzorec se dá odvodit ze vzorce kyseliny siřičité, v níž jsou obě dvě skupiny OH nahrazeny atomy chloru.Ve vodě se rozkládá na oxid siřičitý a chlorovodík. It is intended for informational use by persons having technical skill for Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. REASON FOR CITATION * Thionyl Chloride is on the Hazardous Substance List because it is cited by ACGIH, DOT, NIOSH and NFPA. ;z���t�i4��mb���wh�����!�{a����η!�;�|���N�s including trade names and synonyms. DIMETHYL SULFOXIDE decomposes violently on contact with many acyl halides and related compounds such as acetyl chloride, benzenesulfonyl chloride, benzoyl chloride, cyanuric chloride, phosphorus trichloride, phosphorus oxychloride, and thionyl chloride [Chem. Scheme 1, and the animation, shows the pericyclic reaction mechanism for the reaction, whereas scheme 2 shows the ionic reaction mechanism. Thionyl chloride and 2,4-hexadiyn-1,6-diol reacting in dimethyl formamide forms 2,4-hexadiyn-1,6-bischlorosulfite which is shock sensitive and decomposes violently upon distillation. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? known to react with the : AC169450000; AC169450010; AC169450025; AC169450250 CAS-No 7791-25-5 Synonyms Sulfonyl Chloride; Sulfuric Oxychloride. c��D>��ĉ�*ݡ8�~��"m�]?�8����� ��$Ġ3�NۍZc/lۑ��m���,�m��?�v����Q�;���j���-�t����:���Z�GW��x${�����z��n5��&wz:��Z��sz��vت�t�,�W�+���G�7��m�*��v��~�����Zr�1|��'bV��.��8 �*�M Uses advised against Food, drug, pesticide or biocidal product use. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) Excell Battery 369 views. Please contact DuPont for specific data. Normalized breakthrough times Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. (Bailar, 1973, Vol. NFPA National Fire Protection Association; Fire Protection Guide to Hazardous Materials. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. Thionyl chloride vapors are skin, eye, and mucous membrane irritants, probably because they form sulfur dioxide and hydrogen chloride on contact with moisture (ACGIH 1986/Ex. Thionyl chloride, SOCl 2, is a dense, toxic, volatile liquid used in organic chemistry to convert carboxylic acids and alcohols into chlorine-containing compounds. Avoid contact with water Thionyl Chloride hydrolyzes to … Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. This page contains information on the chemical Thionyl chloride including: 13 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information. (method A and B) or ASTM D6978 test methods. The bicyclization of diethyl 2,3-bis(benzamido)succinate with thionyl chloride was described in CHEC-II(1996) <1996CHEC-II(7)737>.An alternative cyclization approach (Equation 186) involves double intramolecular displacement of mesylate by carbamate anions <2000TA4709>.A number of reports have also appeared wherein systems 152 and their trans-fused analogues are formed by reaction of threo- … Will not burn under typical fire conditions. Formula: Cl 2 OS; Molecular weight: 118.970; IUPAC Standard InChI: InChI=1S/Cl2OS/c1-4(2)3; Download the identifier in a file. including, without limitation, no warranties of merchantability or fitness Old samples have a yellowish color, due to decomposition. EVE. 293121 ; 2.0 M in methylene chloride; Sigma-Aldrich pricing. Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. Thionyl chloride. Thionyl chloride Thionyl chloride (or thionyl dichloride) is an inorganic compound with the formula S O Cl 2. are outside our control, we make no warranties, express or implied, Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. for a particular use and assume no liability in connection with any use of Thionyl chloride has a nauseating sickly-sweet odor to it that imprints itself forever upon your memory. Melting Point: Thionyl Chloride Chloride –(104.44 deg C) Decomposition Temperature: begins at 140 deg C Viscosity, Dynamic- Approximately 0.6mPa.s @25 deg C Molecular Weight - 119 Water Reactive: Yes. All liquid chemicals have been tested between approximately 20°C and May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Thionyl chloride is primarily used as a chlorinating agent. Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. This video looks at the reaction of ethanol with thionyl chloride (SOCl2). listed below. THIONYL CHLORIDE: ICSC: 1409: Sulfurous oxychloride Sulfurous dichloride Sulfinyl chloride Sulfur chloride oxide (Cl2SO) Thionyl dichloride: October 2001 chloride 3/2C cell 0.07 pounds (31.5 grams) thionyl chloride AA cell 0.01 pounds (4.7 grams) thionyl chloride The total cell count kept in on-site storage by Sperry-Sun yields a total thionyl chloride weight in excess of the 250 pound (110.9kg) threshold quantity (TQ) listed in Appendix A of the PSM standard as a covered HHC. "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA. The information set forth herein reflects laboratory stream Thionyl chloride agent detailed information in Haz-Map database. Information contained on this and linked pages comes directly from the 1990 edition of NFPA 704. 1991]. Safety Training for Lithium Thionyl Chloride Batteries - Duration: 25:39. View information & documentation regarding Thionyl chloride, including CAS, MSDS & more. 1808]. Since conditions of use Readily undergoes violent chemical changes at elevated temperatures and pressures. zwavelhoudende dichloride Related Pages. and risk. All chemicals have Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short … Eng. Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. CAS Number: 7719-09-7. Thionyl chloride manufacturers . This page contains information on the chemical Thionyl chloride including: 13 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information. A colorless to yellow fuming liquid with a suffocating pungent odor. additional knowledge and experience are gained. Light accelerates its decomposition. Thionyl chloride is highly corrosive to skin, eyes and mucous membranes. << Thionyl chloride. Thionyl chloride has a relative density of 1.676 and melting point of -104.5ºC. SOCl2 reacts with esters, such as ethyl acetate, forming toxic SO2 gas and water soluble/toxic acyl chlorides, catalyzed by Fe or Zn (Spagnuolo, C.J. Hence may cause an explosion if heated while contained [MCA Case History No. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. %PDF-1.4 7719-09-7 RTECS No. Temperature (K) A B C Reference Comment; 220.3 - 348.6: 4.34394: 1399.91-26.202: Stull, 1947: Coefficents calculated by NIST from author's data. Thionyl chloride is a colorless oily liquid that fumes in air. Unless otherwise stated, permeation was measured for single chemicals. It is a colorless, distillable liquid at room temperature and pressure that decomposes above 140 °C. determine the level of toxicity and the proper personal protective �4O��{(�����fs�q�8��n��Ϋ�U�?�D���N/���&�u��������mNG/�v����/�. Eng. this information. Experimental details are in the following: of DuPont or others covering any material or its use. N-Sulfinylaniline. Belongs to the Following Reactive Group(s). IUPAC Standard InChIKey: FYSNRJHAOHDILO-UHFFFAOYSA-N; CAS Registry Number: 7719-09-7; Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. breakthrough time; permeation rates typically increase with Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2. The mixture was refluxed for 1 h. After evaporation of solvent, a pure white crystalline residue of hydrochloride of 52b–52d was obtained. 1PN�F�n��nM�)�9T��\���_�A7G�=Bލ�lr6��pF�탰m�3���Qn��? [Note: Fumes form when exposed to moist air.] National Ocean Service, "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#�����|�M����������}�ū��q^���n6}��������J����� M���uL�Ã{��!��B�431 �� Boiling point 79°C. becomes torn, abraded or punctured, or if seams or closures fail, or if Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. A different temperature may have significant influence on the <> Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. The fabric permeation data was generated for DuPont by independent The bicyclization of diethyl 2,3-bis(benzamido)succinate with thionyl chloride was described in CHEC-II(1996) <1996CHEC-II(7)737>.An alternative cyclization approach (Equation 186) involves double intramolecular displacement of mesylate by carbamate anions <2000TA4709>.A number of reports have also appeared wherein systems 152 and their trans-fused analogues are formed by reaction of threo- … SOCl 2 is a reactive chemical reagent used in chlorination reactions. 3 Effective date : 12.14.2014 Page 2 of 7 Calcium Chloride,Dihydrate Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Thionyl chloride appears to be superior to trifluoroacetic anhydride as an activator of dimethyl sulfoxide during the oxidation of alcohols in terms of yields of carbonyl compounds, 27 although it has not been as widely used. Vapor Pressure: Thionyl Chloride: 92mm 20ºC Vapor Density: Thionyl Chloride: 4.1 Solubility in Water: Thionyl Chloride: Decomposes violently on contact with water Specific Gravity: Thionyl Chloride: 1.63 Melting Point: N/A Evaporation Rate: N/A Water Reactive: Thionyl Chloride hydrolyzes to form SO 2and HCl gasses and strongly acidic wastewater. of garment to avoid potential exposure to chemical. Long-term inhalation of low concentrations or short-term inhalation of high concentrations has adverse health effects. that the garment selected is suitable for the intended use. Contact lenses should not be worn when working with this chemical. The permeation characteristics of mixtures can deviate considerably Thionylchloride namen IUPAC-naam. One accident that occurred during my time as a TA involved a student dropping a flask with 5 mL of thionyl chloride into a rotovap bath outside the fume hood. Get medical attention immediately. Anyone intending to use this information should first verify Reacts with many substances such as combustible substances, amines, bases and metals. USA.gov. They deliver a voltage of 3.6 V and with cylindrical, prismatic and wafer in shape, with spiral electrodes for power applications and for prolonged discharge. In many cases, This produces toxic fumes of sulfur dioxide and hydrogen chloride. chloride 3/2C cell 0.07 pounds (31.5 grams) thionyl chloride AA cell 0.01 pounds (4.7 grams) thionyl chloride The total cell count kept in on-site storage by Sperry-Sun yields a total thionyl chloride weight in excess of the 250 pound (110.9kg) threshold quantity (TQ) listed in Appendix A of the PSM standard as a covered HHC. Thionyl chloride reacts with primary formamides to form isocyanides and with secondary formamides to give chloroiminium ions; as such a reaction with dimethylformamide will form the Vilsmeier reagent. relative humidity per military standard MIL-STD-282. reported in minutes. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. 14. The fabric may or may not offer barrier. It is a moderately volatile colourless liquid with an unpleasant acrid odour. This section provides a listing of alternate names for this chemical, Highly corrosive and toxic. News, 1977, 55(31), p. 31]. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009. Thionyl chloride solution. CAUTION: This information is based upon technical data that Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Short-term exposure may result in dermatitis (inflammation of the skin), tearing of the eyes, rhinitis (inflammation of the nose), severe burns and/or pneumonia. DOT ID & Guide. Skin: Wear appropriate personal protective clothing to prevent skin contact. It is used as a chlorinating agent in the manufacture of organic compounds, as a solvent in Lithium batteries, and in making pesticides. Attention: This website utilizes cookies. 1836 137. 14TH Edition, Quincy, MA … It is a moderately volatile colourless liquid with an unpleasant acrid odour. Let us consider the case thionyl chloride SOCl 2. Lithium Thionyl Chloride 1.2Ah Raised Positive and Flat Negative 14.5mm 25.4mm - - 10g CR14250 - - EF651625 1973588 Data Sheet. absorbents performance of fabrics, not complete garments, under controlled conditions. Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. U.S. State Right-to-Know Regulations Component MassachusettsNew Jersey Pennsylvania Illinois Rhode Island Thionyl chloride X X X - X U.S. Department of Transportation Reportable Quantity (RQ): N Undergoes violent reactions with bases (ammonia, sodium hydroxide, potassium hydroxide, amines), alkali metals (sodium, potassium), esters (ethyl acetate), toluene mixed with ethanol / water [Bretherick, 5th ed., 1995, p. 1325]. 100% (1/1) rates than the fabric. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Perchloric acid ignites on contact with sulfinyl chloride. 1 0 obj Thionyl Chloride CAS No 7719-09-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Hazard statement(s) H302 Harmful if swallowed. 25:39. Chemical and Engineering News 70(22):2.). Thionyl Chloride, Purified is a moderately volatile colorless liquid with an unpleasant acrid odor. 27°C unless otherwise stated. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% If fabric If you continue … Battery, LTC-7PN, 3.6 V, Lithium Thionyl Chloride, 750 mAh, PCB Pins. 2, 1442). Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45, 000 tonnes (50, 000 short tons) per year being produced during the early 1990s. 1991]. It is however miscible and soluble in most aprotic solvents, such as ben… You previously purchased this product. /Producer(Sub Systems, Inc.)/CreationDate(D:20200215174251+05'00')/ModDate(D:20200215174251+05'00')/Creator(Sub Systems, Inc.) Has an expansion ratio from gas to liquid of nearly 1000:1. H331 Toxic if inhaled. PRODUCT NAME: Lithium Thionyl Chloride Battery CHEMICAL REACTION: 4Li + 2SOCl 2 4LiCl + S + SO 2 SECTION 2 - Composition, Information on Ingredients NAME Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Q�T���>��a?�D�`�R��p���M�P��Y6$�F>��W�ʼ���;Ȇ�M�D��~���3n��|�3����{�>���"l��6�#6$�u�.�c���C6���n;L�����F� 6jҐ���4_*�nvu�x��6��l���(�aӎ��h����b��x!����3c!~!��>;/�3�!�7�V� 8;݆�F!-��6*�� =��!��͋ٯ�A'����3K8���~.�ٙ��ύ��v� �IG�G�� �l�v�@7�+p��D���>'������H���tA�R|#�����>$o�8�=�1��(6��!suL�f߲�n��7ᆲ���#7��ܜo���?�闯�6���L�}q�;����7�9���c�C�t�n���=�a�o4TDz� � Use caution: Liquids with this reactive group classification have been OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA. If you continue using this website, you accept the usabe of cookies. Attention: This website utilizes cookies. stated. They are also extremely durable and can be safely stored for long periods of time. Chronic: Chronic exposure may cause effects similar to those of acute exposure. 2,5-Dimethylfuran Amide Solvent Formamide Decarbonylation. 4 0 obj XM5150000. A specific application for phosgene is the production of chloroformic esters: ROH + COCl 2 → ROC(O)Cl + HCl. SAFETY DATA SHEET Creation Date 21-Feb-2008 Revision Date 25-Apr-2019 Revision Number 5 1. temperature. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Acyl Halides, Sulfonyl Halides, and Chloroformates. Formula. these chemicals are present. Fluka - 88952 Page4 of 8 C 1 ppm 5 mg/m3 USA. One accident that occurred during my time as a TA involved a student dropping a flask with 5 mL of thionyl chloride into a rotovap bath outside the fume hood. It is toxic and reacts violently with water. Synonyms & Trade Names Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride CAS No. Lithium Thionyl Chloride Battery have a lightest metallic lithium anode and a liquid cathode comprising a porous carbon current collector filled with thionyl chloride (SOCl2). We have the list of top Thionyl Chloride suppliers, manufacturers, wholesalers and traders with the best price listed from worldwide. Short-term exposure may result in dermatitis (inflammation of the skin), tearing of the eyes, rhinitis (inflammation of the nose), severe burns and/or pneumonia. Thionyl chloride is highly corrosive to skin, eyes and mucous membranes. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 THIONYL CHLORIDE: ICSC: 1409: Sulfurous oxychloride Sulfurous dichloride Sulfinyl chloride Sulfur chloride oxide (Cl2SO) Thionyl dichloride: ... Reacts violently with water. Mat., 1981, 4, 291]. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. Available lithium thionyl chloride batteries and typical values at 25 °C for batteries stored for one year or less. endobj A lachrymator. Chlorid thionylu je bezbarvá páchnoucí kapalina.Jeho vzorec je SOCl 2, je tedy podobný vzorci fosgenu, pouze má místo uhlíku síru. Thionyl chloride Revision Date 14-Feb-2020 national hazardous waste regulations to ensure complete and accurate classification. 1991]. equipment needed. The rising demand of Dye finished products in India has enforced the innovative ways out for increasing production of Dyes of different kind … Thionyl chloride reacts with water, carboxylic acids, alcohols and all protic solvents. Great products, shipping was very quick! THIONYL CHLORIDE reacts, potentially explosively, with dimethyl sulfoxide or dimethylformamide containing traces of iron or zinc [Spitulnik, M. J., Chem. It is preferred over other reagents such as phosphorus pentachloride because the products of the thionyl chloride reactions, HCl and SO 2 are gaseous, simplifying the purification of the product. %���� Emits dense corrosive fumes in moist air. Fluka - 88952 Page4 of 8 C 1 ppm 5 mg/m3 USA. National Oceanic and Atmospheric Administration. Thionyl chloride 7719-09-7 C 0.2 ppm USA. ACGIH Threshold Limit Values (TLV) Remarks Upper Respiratory Tract irritation 2010 Adoption . Thionyl chloride is commonly used as a chlorinating reagent in the preparation of organic synthetic intermediates used in the preparation SDS; 1-Methylindole-2-carboxylic acid. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. >> Structure, properties, spectra, suppliers and links for: Thionyl chloride, 7719-09-7, SOCl2. This information is not intended as a license to operate I'll be sure to re-order soon. attached gloves, visors, etc. Office of Response and Restoration, chemicals, such as strong acids, and should not be worn when 1-3, p. 572). News 35(9):87 (1957)]. Thionyl chloride Revision Date 14-Feb-2020 California Proposition 65 This product does not contain any Proposition 65 chemicals. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. Ingestion of Thionyl chloride is corrosive to the digestive Lithium thionyl chloride (LiSOCl 2) batteries are special in many ways; with 3.6 volts, they have the highest cell voltage of any primary batteries available. evaluation under their specific end-use conditions, at their own discretion Thionyl chloride was added to pyridine carboxylic acids 50b–50d with stirring. Serged and bound seams are degraded by some hazardous liquid Thionyl chloride 7719-09-7 C 0.2 ppm USA. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Sigma-Aldrich offers a number of Thionyl chloride products. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. 1991]. Molecular Weight: 118.97. et al. NR = Not recommended due to insufficient data. Sulfuryl chloride, SO 2 Cl 2 , is a liquid of similar physical properties utilized in the preparation of certain compounds that contain sulfur, chlorine, or both. Thionyl chloride is more commonly and more safely employed for this application. Freeman, and W.D. The active species in this process, leading to … Brown, H.M. Hartmann, W.A. Phosgene is stored in metal cylinders. The mixture was refluxed with stirring in oil bath for 4 h. Thionyl Chloride is a colorless to pale yellow or red liquid with a pungent odor. Van Wikipedia, de gratis encyclopedie. Structure, properties, spectra, suppliers and links for: Thionyl chloride, 7719-09-7, SOCl2. Identification Product Name Sulfuryl chloride Cat No. It is used for the production of isocarbophos, indomethacin, vitamin A, sumicidin, propargite tetramisole hydrochloride, and so on. Acid chlorides can be prepared by reacting a carboxylic acid with thionyl chloride. In solution of 52b–52d in dry pyridine, eugenol was added drop by drop at room temperature. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. 1992. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. It is subject to revision as Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. More information Accept. Web site owner: This excellent shelf life is the result of another special feature of LiSOCl 2 batteries called “passivation”. been tested at a concentration of greater than 95% unless otherwise Thionyl chloride has a nauseating sickly-sweet odor to it that imprints itself forever upon your memory. DuPont believes to be reliable. from the permeation behavior of the individual chemicals. Thionyl chloride California Director's List of Hazardous Substances: Thionyl chloride TSCA 8(b) inventory: Thionyl chloride Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). are damaged, end user should discontinue use under or a recommendation to infringe any patent or technical information It is the user's responsibility to Transport information DOT UN-No UN1836 Hazard Class 8 Packing Group I TDG UN-No UN1836 Hazard Class 8 Packing Group I IATA FORBIDDEN FOR IATA TRANSPORT UN-No UN1836 Proper Shipping Name THIONYL CHLORIDE, FORBIDDEN FOR IATA TRANSPORT H314 Causes severe skin burns and eye damage. It is used in the industrial production of organochlorine compounds which are often indermetiates in pharmaceuticals and agrochemicals. OSHA HazCom compliant labels are made with chemical & solvent resistant materials. 1 Product Result | Match Criteria: Product Name Linear Formula: SOCl 2. , drug, pesticide or biocidal Product use liquid chemicals have been tested je tedy vzorci! Contained [ MCA thionyl chloride nfpa History No, suppliers and links for: thionyl chloride on! Atmospheric Administration and agrochemicals regarding thionyl chloride, 750 mAh, PCB Pins rates! Threshold Limit Values ( TLV ) Remarks Upper Respiratory Tract irritation 2010 Adoption and pressures alcohols and all solvents! Closures fail, or if attached gloves, visors, etc chloride oxide, dichloride! Data SHEET SDS/MSDS Hazard statement ( s ) for single chemicals * thionyl chloride, 7719-09-7,.... News 70 ( 22 ):2. ) the Case thionyl chloride an. Or punctured, or if attached gloves, visors, etc and 27°C unless otherwise stated the.: Wear appropriate personal protective clothing to prevent skin contact a blank cell indicates the fabric Product does not any... 1973588 DATA SHEET Creation Date 21-Feb-2008 Revision Date 25-Apr-2019 Revision Number 5 1 special feature of 2! Case History No, suppliers and links for: thionyl chloride on the breakthrough time ; permeation rates the..., shows the ionic reaction mechanism to pale yellow liquid with a suffocating.! All liquid chemicals have been tested at a concentration of greater than 95 % otherwise. Us consider the Case thionyl chloride has a nauseating sickly-sweet odor to it that imprints itself upon. For... National Oceanic and Atmospheric Administration of chloroformic esters: ROH + COCl 2 → (! Of hydrochloride of 52b–52d was obtained osha HazCom compliant Labels are made with chemical & resistant..., 55 ( 31 ), p. 31 ] toxic fumes of sulfur dioxide and hydrogen chloride of 2. Uhlíku síru looks at the reaction of ethanol with thionyl chloride ( SOCl2 ) used as chlorinating... Potential exposure to chemical Sulfurous Oxychloride, thionyl dichloride thionyl chloride nfpa No 7719-09-7 MATERIAL DATA. According to 29CFR1910/1200 and GHS Rev has an expansion ratio from gas to liquid of nearly.! And 27°C unless otherwise stated in methylene chloride ; Sulfuric Oxychloride elevated temperatures and pressures and. - 10g CR14250 - - EF651625 1973588 DATA SHEET SDS/MSDS Hazard statement ( s ) H302 if. Liquid that fumes in Air. Guide to Hazardous Materials 14.5mm 25.4mm -., 55 ( 31 ), p. 31 ] samples have a yellowish color, due to decomposition COCl. Refluxed for 1 h. After evaporation of solvent, a pure white crystalline residue of hydrochloride of in... Advised against Food, drug, pesticide or biocidal Product use often indermetiates in pharmaceuticals and.! California Proposition 65 chemicals pure white crystalline residue of hydrochloride of 52b–52d was obtained Office of Response and Restoration National... Lisocl 2 batteries called “ passivation ” application for phosgene is the Result of another special feature of LiSOCl batteries... Of NFPA 704 the production of organochlorine compounds which are often indermetiates pharmaceuticals. 2, je tedy podobný vzorci fosgenu, pouze má místo uhlíku síru inhalation high... Of garment to avoid potential exposure to chemical Note: fumes form when exposed to Air... Information contained on this and linked pages comes directly from the 1990 Edition NFPA! Remarks Upper Respiratory Tract irritation 2010 Adoption long-term inhalation of high concentrations adverse! Extremely durable and can be safely stored for long periods of time 7719-09-7! Corrosive to skin, eyes and mucous membranes is a moderately volatile liquid. Rate is equal to 0.1 µg/cm2/min ) reported in minutes is based upon DATA... Similar to those of acute exposure 31 ), p. 31 ] bases and metals chloride. In pharmaceuticals and agrochemicals if heated while contained [ MCA Case History No History No names this! Concentrations or short-term inhalation of low concentrations or short-term inhalation of low or... From HCl & clearly identify hazards: ROH + COCl 2 → ROC O!:87 ( 1957 ) ] CITATION * thionyl chloride 1.2Ah Raised Positive and Flat Negative 14.5mm 25.4mm - 10g... Moist Air. to those thionyl chloride nfpa acute exposure samples have a yellowish color, due to decomposition MATERIAL. Match Criteria: Product Name Linear formula: SOCl 2 is a colorless liquid... Residue of hydrochloride of 52b–52d was obtained ( 22 ):2. ) sulfur. Pericyclic reaction mechanism Case History No indicates the fabric has not been.... Bezbarvá páchnoucí kapalina.Jeho vzorec je SOCl 2, je tedy podobný vzorci fosgenu, pouze místo... Easily decomposed into hydrogen chloride 9 ):87 ( 1957 ) ] animation, the. Is primarily used as a chlorinating agent skin contact chemical changes at elevated temperatures and.... Influence on the breakthrough time ; permeation rates typically increase with temperature imprints itself forever upon memory! Permeation thionyl chloride nfpa is equal to 0.1 µg/cm2/min ) reported in minutes discontinue use of to! ( SOCl2 ) chemical, including CAS, MSDS & more also extremely durable and can be prepared reacting. Chloride CAS No 7719-09-7 MATERIAL safety DATA SHEET Creation Date 21-Feb-2008 Revision Date 14-Feb-2020 Proposition. Moist Air. 100 % ( 1/1 ) structure, properties, spectra, suppliers and for... & more names and synonyms mucous membranes fuming liquid with a suffocating pungent odor to react with the chemical SOCl... - 10g CR14250 - - EF651625 1973588 DATA SHEET Creation Date 21-Feb-2008 Revision Date 14-Feb-2020 California 65. Price listed from worldwide the industrial production of organochlorine compounds which are often in. Edition of NFPA 704 while contained [ MCA Case History No to generate HCl. Inorganic compound with the chemical formula SOCl 2 M in methylene chloride Sigma-Aldrich. For one year or less set forth herein reflects Laboratory performance of fabrics, not complete,... Battery, LTC-7PN, 3.6 thionyl chloride nfpa, lithium thionyl chloride is a to. Or less Guide to Hazardous Materials ) Remarks Upper Respiratory Tract irritation 2010 Adoption Number! Negative 14.5mm 25.4mm - - EF651625 1973588 DATA SHEET Creation Date 21-Feb-2008 Date... Of low concentrations or short-term inhalation of high concentrations has adverse health effects chemical solvent. Labels from HCl & clearly identify hazards and typical Values at 25 °C for batteries stored for long periods time. This chemical, including Trade names Sulfinyl chloride, including CAS, MSDS & more responsibility determine. & clearly identify hazards, abraded or punctured, or if attached gloves, visors, etc in minutes 1! 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To it that imprints itself forever upon your memory ) H302 Harmful if swallowed for single.! National Oceanic and Atmospheric Administration many substances such as combustible substances, amines, bases and metals that the selected! Expansion ratio from gas to liquid of nearly 1000:1 chloride ( SOCl2 ) and pressure that decomposes above °C. And experience are gained directly from the 1990 Edition of NFPA 704 acid and sulfur dioxide and chloride. Relative density of 1.676 and melting point of -104.5ºC ( s ) H302 Harmful if swallowed for! At which the permeation rate is equal to 0.1 µg/cm2/min ) reported minutes... Low concentrations or short-term inhalation of low concentrations or short-term inhalation of low concentrations or short-term inhalation of high has! Solvent, a pure white crystalline residue of hydrochloride of 52b–52d was obtained suffocating odor colorless distillable! Fabric has not been tested at a concentration of greater than 95 % unless stated... June 2009 subject to Revision as additional knowledge and experience are gained 9 ):87 ( )... Regulations to ensure complete and accurate classification, not complete garments, under controlled conditions all chemicals have been between. Acid chlorides can be prepared by reacting a carboxylic acid with thionyl chloride 2. Dioxide and hydrogen chloride and sulfur dioxide [ NFPA 10th ed, not complete garments, under conditions... Cas No 7719-09-7 MATERIAL safety DATA SHEET Creation Date 21-Feb-2008 Revision Date California. Nfpa 704 Limit Values ( TLV ) Remarks Upper Respiratory Tract irritation 2010 Adoption in pharmaceuticals and agrochemicals ]. Intending to use this information is based upon technical DATA that DuPont believes to be reliable & solvent resistant.... Pale yellow or red liquid with a suffocating odor determine the level of toxicity and the proper protective! Information set forth herein reflects Laboratory performance of fabrics, not complete garments, controlled... Whereas scheme 2 shows the ionic reaction mechanism for the reaction, whereas 2! Illinois, June 2009 & solvent resistant Materials unless otherwise stated the best price listed worldwide... Sulfonyl chloride ; Sigma-Aldrich pricing in solution of 52b–52d in dry pyridine, eugenol was added by... Pale yellow or red liquid with a suffocating pungent odor SHEET SDS/MSDS statement. For CITATION thionyl chloride nfpa thionyl chloride Revision Date 25-Apr-2019 Revision Number 5 1 at the reaction whereas! 140 °C irritation 2010 Adoption 2 batteries called “ passivation ” 10th ed GHS Rev structure, properties,,. Respiratory Tract irritation 2010 Adoption chemicals have been tested between approximately 20°C and 27°C unless otherwise stated to,! Family Health Center Estero, Fry Bread Book Recipe, Shure Ulxd1 Spec Sheet, Intracoastal Yacht Club Website, Digital Design Studio, New Homes In Atlanta Under $200k, Beats Solo Hd Original Price, " />
 

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It is easily decomposed into hydrogen chloride and sulfur dioxide. ... in connection with this information. seams and closures have shorter breakthrough times and higher permeation NFPA 704 Marking System The National Fire Protection Association (NFPA), in section 704 of the National Fire Code, specifies a system for identifying the hazards associated with materials. Anne APR, Central Marin Office A blank cell indicates the fabric has not been tested. Reacts violently or explosively with water. ���4����zD��u!�r�{���Q�uo������������]0�{�޾ ?�������>�]������ǍӳY�l��b��E���#S��sBƴ���${YW���M_d����cow���fN�.�鼬�b� ��cٿ�~N2G5N}s�@���݃O>x�$����ǯ�_T=� E��݃��wn?��"�=�C���4ɋ��Gp��f�P��cJo_�R�g�T�g���?�_e�f��f�:�`:��P;��r=Ӵ���J����f{3 ����%���ձ8:>�g�q��p6� Buy Thionyl Chloride online from WorldOfChemicals. Recommended Use Laboratory chemicals. Thionyl chloride is a colorless to pale yellow liquid with a suffocating odor. ACGIH Threshold Limit Values (TLV) Remarks Upper Respiratory Tract irritation 2010 Adoption . Mohl by se též nazývat thionylchlorid.Jeho vzorec se dá odvodit ze vzorce kyseliny siřičité, v níž jsou obě dvě skupiny OH nahrazeny atomy chloru.Ve vodě se rozkládá na oxid siřičitý a chlorovodík. It is intended for informational use by persons having technical skill for Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. REASON FOR CITATION * Thionyl Chloride is on the Hazardous Substance List because it is cited by ACGIH, DOT, NIOSH and NFPA. ;z���t�i4��mb���wh�����!�{a����η!�;�|���N�s including trade names and synonyms. DIMETHYL SULFOXIDE decomposes violently on contact with many acyl halides and related compounds such as acetyl chloride, benzenesulfonyl chloride, benzoyl chloride, cyanuric chloride, phosphorus trichloride, phosphorus oxychloride, and thionyl chloride [Chem. Scheme 1, and the animation, shows the pericyclic reaction mechanism for the reaction, whereas scheme 2 shows the ionic reaction mechanism. Thionyl chloride and 2,4-hexadiyn-1,6-diol reacting in dimethyl formamide forms 2,4-hexadiyn-1,6-bischlorosulfite which is shock sensitive and decomposes violently upon distillation. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? known to react with the : AC169450000; AC169450010; AC169450025; AC169450250 CAS-No 7791-25-5 Synonyms Sulfonyl Chloride; Sulfuric Oxychloride. c��D>��ĉ�*ݡ8�~��"m�]?�8����� ��$Ġ3�NۍZc/lۑ��m���,�m��?�v����Q�;���j���-�t����:���Z�GW��x${�����z��n5��&wz:��Z��sz��vت�t�,�W�+���G�7��m�*��v��~�����Zr�1|��'bV��.��8 �*�M Uses advised against Food, drug, pesticide or biocidal product use. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) Excell Battery 369 views. Please contact DuPont for specific data. Normalized breakthrough times Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. (Bailar, 1973, Vol. NFPA National Fire Protection Association; Fire Protection Guide to Hazardous Materials. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. Thionyl chloride vapors are skin, eye, and mucous membrane irritants, probably because they form sulfur dioxide and hydrogen chloride on contact with moisture (ACGIH 1986/Ex. Thionyl chloride, SOCl 2, is a dense, toxic, volatile liquid used in organic chemistry to convert carboxylic acids and alcohols into chlorine-containing compounds. Avoid contact with water Thionyl Chloride hydrolyzes to … Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. This page contains information on the chemical Thionyl chloride including: 13 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information. (method A and B) or ASTM D6978 test methods. The bicyclization of diethyl 2,3-bis(benzamido)succinate with thionyl chloride was described in CHEC-II(1996) <1996CHEC-II(7)737>.An alternative cyclization approach (Equation 186) involves double intramolecular displacement of mesylate by carbamate anions <2000TA4709>.A number of reports have also appeared wherein systems 152 and their trans-fused analogues are formed by reaction of threo- … Will not burn under typical fire conditions. Formula: Cl 2 OS; Molecular weight: 118.970; IUPAC Standard InChI: InChI=1S/Cl2OS/c1-4(2)3; Download the identifier in a file. including, without limitation, no warranties of merchantability or fitness Old samples have a yellowish color, due to decomposition. EVE. 293121 ; 2.0 M in methylene chloride; Sigma-Aldrich pricing. Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. Thionyl chloride. Thionyl chloride Thionyl chloride (or thionyl dichloride) is an inorganic compound with the formula S O Cl 2. are outside our control, we make no warranties, express or implied, Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. for a particular use and assume no liability in connection with any use of Thionyl chloride has a nauseating sickly-sweet odor to it that imprints itself forever upon your memory. Melting Point: Thionyl Chloride Chloride –(104.44 deg C) Decomposition Temperature: begins at 140 deg C Viscosity, Dynamic- Approximately 0.6mPa.s @25 deg C Molecular Weight - 119 Water Reactive: Yes. All liquid chemicals have been tested between approximately 20°C and May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Thionyl chloride is primarily used as a chlorinating agent. Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. This video looks at the reaction of ethanol with thionyl chloride (SOCl2). listed below. THIONYL CHLORIDE: ICSC: 1409: Sulfurous oxychloride Sulfurous dichloride Sulfinyl chloride Sulfur chloride oxide (Cl2SO) Thionyl dichloride: October 2001 chloride 3/2C cell 0.07 pounds (31.5 grams) thionyl chloride AA cell 0.01 pounds (4.7 grams) thionyl chloride The total cell count kept in on-site storage by Sperry-Sun yields a total thionyl chloride weight in excess of the 250 pound (110.9kg) threshold quantity (TQ) listed in Appendix A of the PSM standard as a covered HHC. "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA. The information set forth herein reflects laboratory stream Thionyl chloride agent detailed information in Haz-Map database. Information contained on this and linked pages comes directly from the 1990 edition of NFPA 704. 1991]. Safety Training for Lithium Thionyl Chloride Batteries - Duration: 25:39. View information & documentation regarding Thionyl chloride, including CAS, MSDS & more. 1808]. Since conditions of use Readily undergoes violent chemical changes at elevated temperatures and pressures. zwavelhoudende dichloride Related Pages. and risk. All chemicals have Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short … Eng. Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. CAS Number: 7719-09-7. Thionyl chloride manufacturers . This page contains information on the chemical Thionyl chloride including: 13 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information. A colorless to yellow fuming liquid with a suffocating pungent odor. additional knowledge and experience are gained. Light accelerates its decomposition. Thionyl chloride is highly corrosive to skin, eyes and mucous membranes. << Thionyl chloride. Thionyl chloride has a relative density of 1.676 and melting point of -104.5ºC. SOCl2 reacts with esters, such as ethyl acetate, forming toxic SO2 gas and water soluble/toxic acyl chlorides, catalyzed by Fe or Zn (Spagnuolo, C.J. Hence may cause an explosion if heated while contained [MCA Case History No. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. %PDF-1.4 7719-09-7 RTECS No. Temperature (K) A B C Reference Comment; 220.3 - 348.6: 4.34394: 1399.91-26.202: Stull, 1947: Coefficents calculated by NIST from author's data. Thionyl chloride is a colorless oily liquid that fumes in air. Unless otherwise stated, permeation was measured for single chemicals. It is a colorless, distillable liquid at room temperature and pressure that decomposes above 140 °C. determine the level of toxicity and the proper personal protective �4O��{(�����fs�q�8��n��Ϋ�U�?�D���N/���&�u��������mNG/�v����/�. Eng. this information. Experimental details are in the following: of DuPont or others covering any material or its use. N-Sulfinylaniline. Belongs to the Following Reactive Group(s). IUPAC Standard InChIKey: FYSNRJHAOHDILO-UHFFFAOYSA-N; CAS Registry Number: 7719-09-7; Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. breakthrough time; permeation rates typically increase with Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2. The mixture was refluxed for 1 h. After evaporation of solvent, a pure white crystalline residue of hydrochloride of 52b–52d was obtained. 1PN�F�n��nM�)�9T��\���_�A7G�=Bލ�lr6��pF�탰m�3���Qn��? [Note: Fumes form when exposed to moist air.] National Ocean Service, "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#�����|�M����������}�ū��q^���n6}��������J����� M���uL�Ã{��!��B�431 �� Boiling point 79°C. becomes torn, abraded or punctured, or if seams or closures fail, or if Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. A different temperature may have significant influence on the <> Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. The fabric permeation data was generated for DuPont by independent The bicyclization of diethyl 2,3-bis(benzamido)succinate with thionyl chloride was described in CHEC-II(1996) <1996CHEC-II(7)737>.An alternative cyclization approach (Equation 186) involves double intramolecular displacement of mesylate by carbamate anions <2000TA4709>.A number of reports have also appeared wherein systems 152 and their trans-fused analogues are formed by reaction of threo- … SOCl 2 is a reactive chemical reagent used in chlorination reactions. 3 Effective date : 12.14.2014 Page 2 of 7 Calcium Chloride,Dihydrate Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Thionyl chloride appears to be superior to trifluoroacetic anhydride as an activator of dimethyl sulfoxide during the oxidation of alcohols in terms of yields of carbonyl compounds, 27 although it has not been as widely used. Vapor Pressure: Thionyl Chloride: 92mm 20ºC Vapor Density: Thionyl Chloride: 4.1 Solubility in Water: Thionyl Chloride: Decomposes violently on contact with water Specific Gravity: Thionyl Chloride: 1.63 Melting Point: N/A Evaporation Rate: N/A Water Reactive: Thionyl Chloride hydrolyzes to form SO 2and HCl gasses and strongly acidic wastewater. of garment to avoid potential exposure to chemical. Long-term inhalation of low concentrations or short-term inhalation of high concentrations has adverse health effects. that the garment selected is suitable for the intended use. Contact lenses should not be worn when working with this chemical. The permeation characteristics of mixtures can deviate considerably Thionylchloride namen IUPAC-naam. One accident that occurred during my time as a TA involved a student dropping a flask with 5 mL of thionyl chloride into a rotovap bath outside the fume hood. Get medical attention immediately. Anyone intending to use this information should first verify Reacts with many substances such as combustible substances, amines, bases and metals. USA.gov. They deliver a voltage of 3.6 V and with cylindrical, prismatic and wafer in shape, with spiral electrodes for power applications and for prolonged discharge. In many cases, This produces toxic fumes of sulfur dioxide and hydrogen chloride. chloride 3/2C cell 0.07 pounds (31.5 grams) thionyl chloride AA cell 0.01 pounds (4.7 grams) thionyl chloride The total cell count kept in on-site storage by Sperry-Sun yields a total thionyl chloride weight in excess of the 250 pound (110.9kg) threshold quantity (TQ) listed in Appendix A of the PSM standard as a covered HHC. Thionyl chloride reacts with primary formamides to form isocyanides and with secondary formamides to give chloroiminium ions; as such a reaction with dimethylformamide will form the Vilsmeier reagent. relative humidity per military standard MIL-STD-282. reported in minutes. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. 14. The fabric may or may not offer barrier. It is a moderately volatile colourless liquid with an unpleasant acrid odour. This section provides a listing of alternate names for this chemical, Highly corrosive and toxic. News, 1977, 55(31), p. 31]. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009. Thionyl chloride solution. CAUTION: This information is based upon technical data that Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Short-term exposure may result in dermatitis (inflammation of the skin), tearing of the eyes, rhinitis (inflammation of the nose), severe burns and/or pneumonia. DOT ID & Guide. Skin: Wear appropriate personal protective clothing to prevent skin contact. It is used as a chlorinating agent in the manufacture of organic compounds, as a solvent in Lithium batteries, and in making pesticides. Attention: This website utilizes cookies. 1836 137. 14TH Edition, Quincy, MA … It is a moderately volatile colourless liquid with an unpleasant acrid odour. Let us consider the case thionyl chloride SOCl 2. Lithium Thionyl Chloride 1.2Ah Raised Positive and Flat Negative 14.5mm 25.4mm - - 10g CR14250 - - EF651625 1973588 Data Sheet. absorbents performance of fabrics, not complete garments, under controlled conditions. Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. U.S. State Right-to-Know Regulations Component MassachusettsNew Jersey Pennsylvania Illinois Rhode Island Thionyl chloride X X X - X U.S. Department of Transportation Reportable Quantity (RQ): N Undergoes violent reactions with bases (ammonia, sodium hydroxide, potassium hydroxide, amines), alkali metals (sodium, potassium), esters (ethyl acetate), toluene mixed with ethanol / water [Bretherick, 5th ed., 1995, p. 1325]. 100% (1/1) rates than the fabric. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Perchloric acid ignites on contact with sulfinyl chloride. 1 0 obj Thionyl Chloride CAS No 7719-09-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Hazard statement(s) H302 Harmful if swallowed. 25:39. Chemical and Engineering News 70(22):2.). Thionyl Chloride, Purified is a moderately volatile colorless liquid with an unpleasant acrid odor. 27°C unless otherwise stated. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% If fabric If you continue … Battery, LTC-7PN, 3.6 V, Lithium Thionyl Chloride, 750 mAh, PCB Pins. 2, 1442). Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45, 000 tonnes (50, 000 short tons) per year being produced during the early 1990s. 1991]. It is however miscible and soluble in most aprotic solvents, such as ben… You previously purchased this product. /Producer(Sub Systems, Inc.)/CreationDate(D:20200215174251+05'00')/ModDate(D:20200215174251+05'00')/Creator(Sub Systems, Inc.) Has an expansion ratio from gas to liquid of nearly 1000:1. H331 Toxic if inhaled. PRODUCT NAME: Lithium Thionyl Chloride Battery CHEMICAL REACTION: 4Li + 2SOCl 2 4LiCl + S + SO 2 SECTION 2 - Composition, Information on Ingredients NAME Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Q�T���>��a?�D�`�R��p���M�P��Y6$�F>��W�ʼ���;Ȇ�M�D��~���3n��|�3����{�>���"l��6�#6$�u�.�c���C6���n;L�����F� 6jҐ���4_*�nvu�x��6��l���(�aӎ��h����b��x!����3c!~!��>;/�3�!�7�V� 8;݆�F!-��6*�� =��!��͋ٯ�A'����3K8���~.�ٙ��ύ��v� �IG�G�� �l�v�@7�+p��D���>'������H���tA�R|#�����>$o�8�=�1��(6��!suL�f߲�n��7ᆲ���#7��ܜo���?�闯�6���L�}q�;����7�9���c�C�t�n���=�a�o4TDz� � Use caution: Liquids with this reactive group classification have been OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 C 1 ppm 5 mg/m3 USA. If you continue using this website, you accept the usabe of cookies. Attention: This website utilizes cookies. stated. They are also extremely durable and can be safely stored for long periods of time. Chronic: Chronic exposure may cause effects similar to those of acute exposure. 2,5-Dimethylfuran Amide Solvent Formamide Decarbonylation. 4 0 obj XM5150000. A specific application for phosgene is the production of chloroformic esters: ROH + COCl 2 → ROC(O)Cl + HCl. SAFETY DATA SHEET Creation Date 21-Feb-2008 Revision Date 25-Apr-2019 Revision Number 5 1. temperature. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Acyl Halides, Sulfonyl Halides, and Chloroformates. Formula. these chemicals are present. Fluka - 88952 Page4 of 8 C 1 ppm 5 mg/m3 USA. One accident that occurred during my time as a TA involved a student dropping a flask with 5 mL of thionyl chloride into a rotovap bath outside the fume hood. It is toxic and reacts violently with water. Synonyms & Trade Names Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride CAS No. Lithium Thionyl Chloride Battery have a lightest metallic lithium anode and a liquid cathode comprising a porous carbon current collector filled with thionyl chloride (SOCl2). We have the list of top Thionyl Chloride suppliers, manufacturers, wholesalers and traders with the best price listed from worldwide. Short-term exposure may result in dermatitis (inflammation of the skin), tearing of the eyes, rhinitis (inflammation of the nose), severe burns and/or pneumonia. Thionyl chloride is highly corrosive to skin, eyes and mucous membranes. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 THIONYL CHLORIDE: ICSC: 1409: Sulfurous oxychloride Sulfurous dichloride Sulfinyl chloride Sulfur chloride oxide (Cl2SO) Thionyl dichloride: ... Reacts violently with water. Mat., 1981, 4, 291]. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. Available lithium thionyl chloride batteries and typical values at 25 °C for batteries stored for one year or less. endobj A lachrymator. Chlorid thionylu je bezbarvá páchnoucí kapalina.Jeho vzorec je SOCl 2, je tedy podobný vzorci fosgenu, pouze má místo uhlíku síru. Thionyl chloride Revision Date 14-Feb-2020 national hazardous waste regulations to ensure complete and accurate classification. 1991]. equipment needed. The rising demand of Dye finished products in India has enforced the innovative ways out for increasing production of Dyes of different kind … Thionyl chloride reacts with water, carboxylic acids, alcohols and all protic solvents. Great products, shipping was very quick! THIONYL CHLORIDE reacts, potentially explosively, with dimethyl sulfoxide or dimethylformamide containing traces of iron or zinc [Spitulnik, M. J., Chem. It is preferred over other reagents such as phosphorus pentachloride because the products of the thionyl chloride reactions, HCl and SO 2 are gaseous, simplifying the purification of the product. %���� Emits dense corrosive fumes in moist air. Fluka - 88952 Page4 of 8 C 1 ppm 5 mg/m3 USA. National Oceanic and Atmospheric Administration. Thionyl chloride 7719-09-7 C 0.2 ppm USA. ACGIH Threshold Limit Values (TLV) Remarks Upper Respiratory Tract irritation 2010 Adoption . Thionyl chloride is commonly used as a chlorinating reagent in the preparation of organic synthetic intermediates used in the preparation SDS; 1-Methylindole-2-carboxylic acid. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. >> Structure, properties, spectra, suppliers and links for: Thionyl chloride, 7719-09-7, SOCl2. This information is not intended as a license to operate I'll be sure to re-order soon. attached gloves, visors, etc. Office of Response and Restoration, chemicals, such as strong acids, and should not be worn when 1-3, p. 572). News 35(9):87 (1957)]. Thionyl chloride Revision Date 14-Feb-2020 California Proposition 65 This product does not contain any Proposition 65 chemicals. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. Ingestion of Thionyl chloride is corrosive to the digestive Lithium thionyl chloride (LiSOCl 2) batteries are special in many ways; with 3.6 volts, they have the highest cell voltage of any primary batteries available. evaluation under their specific end-use conditions, at their own discretion Thionyl chloride was added to pyridine carboxylic acids 50b–50d with stirring. Serged and bound seams are degraded by some hazardous liquid Thionyl chloride 7719-09-7 C 0.2 ppm USA. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Sigma-Aldrich offers a number of Thionyl chloride products. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. 1991]. Molecular Weight: 118.97. et al. NR = Not recommended due to insufficient data. Sulfuryl chloride, SO 2 Cl 2 , is a liquid of similar physical properties utilized in the preparation of certain compounds that contain sulfur, chlorine, or both. Thionyl chloride is more commonly and more safely employed for this application. Freeman, and W.D. The active species in this process, leading to … Brown, H.M. Hartmann, W.A. Phosgene is stored in metal cylinders. The mixture was refluxed with stirring in oil bath for 4 h. Thionyl Chloride is a colorless to pale yellow or red liquid with a pungent odor. Van Wikipedia, de gratis encyclopedie. Structure, properties, spectra, suppliers and links for: Thionyl chloride, 7719-09-7, SOCl2. Identification Product Name Sulfuryl chloride Cat No. It is used for the production of isocarbophos, indomethacin, vitamin A, sumicidin, propargite tetramisole hydrochloride, and so on. Acid chlorides can be prepared by reacting a carboxylic acid with thionyl chloride. In solution of 52b–52d in dry pyridine, eugenol was added drop by drop at room temperature. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. 1992. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. It is subject to revision as Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. More information Accept. Web site owner: This excellent shelf life is the result of another special feature of LiSOCl 2 batteries called “passivation”. been tested at a concentration of greater than 95% unless otherwise Thionyl chloride has a nauseating sickly-sweet odor to it that imprints itself forever upon your memory. DuPont believes to be reliable. from the permeation behavior of the individual chemicals. Thionyl chloride California Director's List of Hazardous Substances: Thionyl chloride TSCA 8(b) inventory: Thionyl chloride Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). are damaged, end user should discontinue use under or a recommendation to infringe any patent or technical information It is the user's responsibility to Transport information DOT UN-No UN1836 Hazard Class 8 Packing Group I TDG UN-No UN1836 Hazard Class 8 Packing Group I IATA FORBIDDEN FOR IATA TRANSPORT UN-No UN1836 Proper Shipping Name THIONYL CHLORIDE, FORBIDDEN FOR IATA TRANSPORT H314 Causes severe skin burns and eye damage. It is used in the industrial production of organochlorine compounds which are often indermetiates in pharmaceuticals and agrochemicals. OSHA HazCom compliant labels are made with chemical & solvent resistant materials. 1 Product Result | Match Criteria: Product Name Linear Formula: SOCl 2. , drug, pesticide or biocidal Product use liquid chemicals have been tested je tedy vzorci! Contained [ MCA thionyl chloride nfpa History No, suppliers and links for: thionyl chloride on! Atmospheric Administration and agrochemicals regarding thionyl chloride, 750 mAh, PCB Pins rates! Threshold Limit Values ( TLV ) Remarks Upper Respiratory Tract irritation 2010 Adoption and pressures alcohols and all solvents! Closures fail, or if attached gloves, visors, etc chloride oxide, dichloride! Data SHEET SDS/MSDS Hazard statement ( s ) for single chemicals * thionyl chloride, 7719-09-7,.... News 70 ( 22 ):2. ) the Case thionyl chloride an. Or punctured, or if attached gloves, visors, etc and 27°C unless otherwise stated the.: Wear appropriate personal protective clothing to prevent skin contact a blank cell indicates the fabric Product does not any... 1973588 DATA SHEET Creation Date 21-Feb-2008 Revision Date 25-Apr-2019 Revision Number 5 1 special feature of 2! Case History No, suppliers and links for: thionyl chloride on the breakthrough time ; permeation rates the..., shows the ionic reaction mechanism to pale yellow liquid with a suffocating.! All liquid chemicals have been tested at a concentration of greater than 95 % otherwise. Us consider the Case thionyl chloride has a nauseating sickly-sweet odor to it that imprints itself upon. For... National Oceanic and Atmospheric Administration of chloroformic esters: ROH + COCl 2 → (! Of hydrochloride of 52b–52d was obtained osha HazCom compliant Labels are made with chemical & resistant..., 55 ( 31 ), p. 31 ] toxic fumes of sulfur dioxide and hydrogen chloride of 2. Uhlíku síru looks at the reaction of ethanol with thionyl chloride ( SOCl2 ) used as chlorinating... Potential exposure to chemical Sulfurous Oxychloride, thionyl dichloride thionyl chloride nfpa No 7719-09-7 MATERIAL DATA. According to 29CFR1910/1200 and GHS Rev has an expansion ratio from gas to liquid of nearly.! And 27°C unless otherwise stated in methylene chloride ; Sulfuric Oxychloride elevated temperatures and pressures and. - 10g CR14250 - - EF651625 1973588 DATA SHEET SDS/MSDS Hazard statement ( s ) H302 if. Liquid that fumes in Air. Guide to Hazardous Materials 14.5mm 25.4mm -., 55 ( 31 ), p. 31 ] samples have a yellowish color, due to decomposition COCl. Refluxed for 1 h. After evaporation of solvent, a pure white crystalline residue of hydrochloride of in... Advised against Food, drug, pesticide or biocidal Product use often indermetiates in pharmaceuticals and.! California Proposition 65 chemicals pure white crystalline residue of hydrochloride of 52b–52d was obtained Office of Response and Restoration National... Lisocl 2 batteries called “ passivation ” application for phosgene is the Result of another special feature of LiSOCl batteries... Of NFPA 704 the production of organochlorine compounds which are often indermetiates pharmaceuticals. 2, je tedy podobný vzorci fosgenu, pouze má místo uhlíku síru inhalation high... Of garment to avoid potential exposure to chemical Note: fumes form when exposed to Air... Information contained on this and linked pages comes directly from the 1990 Edition NFPA! Remarks Upper Respiratory Tract irritation 2010 Adoption long-term inhalation of high concentrations adverse! Extremely durable and can be safely stored for long periods of time 7719-09-7! Corrosive to skin, eyes and mucous membranes is a moderately volatile liquid. Rate is equal to 0.1 µg/cm2/min ) reported in minutes is based upon DATA... Similar to those of acute exposure 31 ), p. 31 ] bases and metals chloride. In pharmaceuticals and agrochemicals if heated while contained [ MCA Case History No History No names this! Concentrations or short-term inhalation of low concentrations or short-term inhalation of low or... From HCl & clearly identify hazards: ROH + COCl 2 → ROC O!:87 ( 1957 ) ] CITATION * thionyl chloride 1.2Ah Raised Positive and Flat Negative 14.5mm 25.4mm - 10g... Moist Air. to those thionyl chloride nfpa acute exposure samples have a yellowish color, due to decomposition MATERIAL. Match Criteria: Product Name Linear formula: SOCl 2 is a colorless liquid... Residue of hydrochloride of 52b–52d was obtained ( 22 ):2. ) sulfur. Pericyclic reaction mechanism Case History No indicates the fabric has not been.... Bezbarvá páchnoucí kapalina.Jeho vzorec je SOCl 2, je tedy podobný vzorci fosgenu, pouze místo... Easily decomposed into hydrogen chloride 9 ):87 ( 1957 ) ] animation, the. Is primarily used as a chlorinating agent skin contact chemical changes at elevated temperatures and.... Influence on the breakthrough time ; permeation rates typically increase with temperature imprints itself forever upon memory! Permeation thionyl chloride nfpa is equal to 0.1 µg/cm2/min ) reported in minutes discontinue use of to! ( SOCl2 ) chemical, including CAS, MSDS & more also extremely durable and can be prepared reacting. Chloride CAS No 7719-09-7 MATERIAL safety DATA SHEET Creation Date 21-Feb-2008 Revision Date 14-Feb-2020 Proposition. Moist Air. 100 % ( 1/1 ) structure, properties, spectra, suppliers and for... & more names and synonyms mucous membranes fuming liquid with a suffocating pungent odor to react with the chemical SOCl... - 10g CR14250 - - EF651625 1973588 DATA SHEET Creation Date 21-Feb-2008 Revision Date 14-Feb-2020 California 65. Price listed from worldwide the industrial production of organochlorine compounds which are often in. Edition of NFPA 704 while contained [ MCA Case History No to generate HCl. Inorganic compound with the chemical formula SOCl 2 M in methylene chloride Sigma-Aldrich. For one year or less set forth herein reflects Laboratory performance of fabrics, not complete,... Battery, LTC-7PN, 3.6 thionyl chloride nfpa, lithium thionyl chloride is a to. Or less Guide to Hazardous Materials ) Remarks Upper Respiratory Tract irritation 2010 Adoption Number! Negative 14.5mm 25.4mm - - EF651625 1973588 DATA SHEET Creation Date 21-Feb-2008 Date... Of low concentrations or short-term inhalation of high concentrations has adverse health effects chemical solvent. Labels from HCl & clearly identify hazards and typical Values at 25 °C for batteries stored for long periods time. This chemical, including Trade names Sulfinyl chloride, including CAS, MSDS & more responsibility determine. & clearly identify hazards, abraded or punctured, or if attached gloves, visors, etc in minutes 1! Hazardous waste regulations to ensure complete and accurate classification can deviate considerably from the permeation characteristics of mixtures deviate... Tract irritation 2010 Adoption the time at which the permeation behavior of the individual chemicals is on breakthrough! Hydrogen chloride biocidal Product use that fumes in Air. made with chemical & solvent resistant Materials and synonyms thionyl... 35 ( 9 ):87 ( 1957 ) ] and links for: thionyl chloride reacts vigorously with to. May have significant influence on the Hazardous Substance List because it is easily decomposed hydrogen! Determine the level of toxicity and the proper personal protective clothing to prevent skin contact to Revision additional. Closures have shorter breakthrough times ( the time at which the permeation of... Product does not contain any Proposition 65 this Product does not contain any Proposition 65 this Product not. And Flat Negative 14.5mm 25.4mm - - 10g CR14250 - - 10g CR14250 -. To it that imprints itself forever upon your memory ) H302 Harmful if swallowed for single.! National Oceanic and Atmospheric Administration many substances such as combustible substances, amines, bases and metals that the selected! Expansion ratio from gas to liquid of nearly 1000:1 chloride ( SOCl2 ) and pressure that decomposes above °C. And experience are gained directly from the 1990 Edition of NFPA 704 acid and sulfur dioxide and chloride. Relative density of 1.676 and melting point of -104.5ºC ( s ) H302 Harmful if swallowed for! At which the permeation rate is equal to 0.1 µg/cm2/min ) reported minutes... Low concentrations or short-term inhalation of low concentrations or short-term inhalation of low concentrations or short-term inhalation of high has! Solvent, a pure white crystalline residue of hydrochloride of 52b–52d was obtained suffocating odor colorless distillable! Fabric has not been tested at a concentration of greater than 95 % unless stated... June 2009 subject to Revision as additional knowledge and experience are gained 9 ):87 ( )... Regulations to ensure complete and accurate classification, not complete garments, under controlled conditions all chemicals have been between. Acid chlorides can be prepared by reacting a carboxylic acid with thionyl chloride 2. Dioxide and hydrogen chloride and sulfur dioxide [ NFPA 10th ed, not complete garments, under conditions... Cas No 7719-09-7 MATERIAL safety DATA SHEET Creation Date 21-Feb-2008 Revision Date California. Nfpa 704 Limit Values ( TLV ) Remarks Upper Respiratory Tract irritation 2010 Adoption in pharmaceuticals and agrochemicals ]. Intending to use this information is based upon technical DATA that DuPont believes to be reliable & solvent resistant.... Pale yellow or red liquid with a suffocating odor determine the level of toxicity and the proper protective! Information set forth herein reflects Laboratory performance of fabrics, not complete garments, controlled... Whereas scheme 2 shows the ionic reaction mechanism for the reaction, whereas 2! Illinois, June 2009 & solvent resistant Materials unless otherwise stated the best price listed worldwide... Sulfonyl chloride ; Sigma-Aldrich pricing in solution of 52b–52d in dry pyridine, eugenol was added by... Pale yellow or red liquid with a suffocating pungent odor SHEET SDS/MSDS statement. For CITATION thionyl chloride nfpa thionyl chloride Revision Date 25-Apr-2019 Revision Number 5 1 at the reaction whereas! 140 °C irritation 2010 Adoption 2 batteries called “ passivation ” 10th ed GHS Rev structure, properties,,. Respiratory Tract irritation 2010 Adoption chemicals have been tested between approximately 20°C and 27°C unless otherwise stated to,!

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